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Pd2(dba)3/P(MeNCH2CH2)3N·HCl-mediated Stille cross-coupling of [1-11C]acetyl chloride with aryl and heteroaryl stannanes

✍ Scribed by Takuya Arai


Book ID
116799840
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
469 KB
Volume
39
Category
Article
ISSN
0969-8051

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Pd/P(i-BuNCH2CH2)3N: an efficient cataly
✍ Sameer Urgaonkar; M. Nagarajan; J.G. Verkade 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 123 KB

Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can