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Pd 2 (dba) 3 /P( i -BuNCH 2 CH 2 ) 3 N-Catalyzed Stille Cross-Coupling of Aryl Chlorides

✍ Scribed by Su, Weiping; Urgaonkar, Sameer; Verkade, John G.

Book ID: 119998015
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 79 KB
Volume: 6
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol0495927

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Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can