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Pd(0)-Catalyzed Amphiphilic Allylation of Aldehydes with Vinyl Epoxide.

โœ Scribed by Masanari Kimura; Ryutaro Mukai; Takato Tamaki; Yoshikazu Horino; Yoshinao Tamaru


Publisher
John Wiley and Sons
Year
2007
Weight
50 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœ I. SHIBATA; S. FUKUOKA; A. BABA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 38 KB ๐Ÿ‘ 1 views

Simple Synthetic Method of Allyl-and Vinyl-Epoxides by Allylation of Carbonyl Groups with Allylic Tins Catalyzed by PbI 2 -HMPA. -The PbI 2 -HMPA catalyzed chemoselective carbonyl-allylation in ฮฑ-halo ketones to achieve one-pot preparation of allyl epoxides (III) is presented. Moreover a simple and