Pb(OAc)4 mediated oxidative cleavage of steroidal unsaturated 1,2-diols: influence of the angular substitution

✍ Scribed by Maria del Rosario Rico Ferreira; JoséIgnacio Martín Hernando; JoséIgnacio Candela Lena; Loïc Toupet; Nicolas Birlirakis; Siméon Arseniyadis

• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 241 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)01565-8

✦ Synopsis

To evaluate the effect of angular substitution at C-10, the required precursor 2b was prepared by the methods described earlier and subjected to oxidative cleavage with lead tetraacetate.