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ChemInform Abstract: Modified Steroids: Pb(OAc)4-Mediated One-Pot Multistage Transformations of Steroidal Unsaturated 1,2-Diols.

✍ Scribed by Maria del Rosario Rico Ferreira; Ignacio Jose Martin Hernando; Jose Ignacio Candela Lena; Jose Quilez del Moral; Simeon Arseniyadis

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199939163

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Pb(OAc)4 mediated oxidative cleavage of

Pb(OAc)4 mediated oxidative cleavage of steroidal unsaturated 1,2-diols: influence of the angular substitution

✍ Maria del Rosario Rico Ferreira; JoséIgnacio Martín Hernando; JoséIgnacio Candel 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 241 KB

To evaluate the effect of angular substitution at C-10, the required precursor 2b was prepared by the methods described earlier and subjected to oxidative cleavage with lead tetraacetate.

ChemInform Abstract: Lead Tetraacetate M

ChemInform Abstract: Lead Tetraacetate Mediated “One-Pot” Multistage Transformations on Selected Unsaturated 1,2-Diols: The Wieland—Miescher Series.

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ChemInform Abstract: Manganese Dioxide M

ChemInform Abstract: Manganese Dioxide Mediated Stereoselective, One-Step Synthesis of Novel Steroidal (6R)-Spiro-1′,2′,4′-triazoline-3′-thiones.

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ChemInform Abstract: Pd(OAc)2-Catalyzed

ChemInform Abstract: Pd(OAc)2-Catalyzed Cyclization of 2,3-Allenoic Acids in the Presence of Terminal α,β-Unsaturated Alkynones: A One-Pot Highly Stereoselective Synthesis of 4-(3′-Oxo-1′(E)-alkenyl)-2(5H)-furanones.

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