## Abstract For Abstract see ChemInform Abstract in Full Text.
Pauson–Khand reactions catalyzed by entrapped rhodium complexes
✍ Scribed by Kang Hyun Park; Seung Uk Son; Young Keun Chung
- Book ID
- 104253298
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 111 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
An entrapped Rh complex prepared by a sol-gel process has been used as a catalyst in the Pauson-Khand reaction under mild reaction conditions; the catalyst is easily recovered and reused at least 10 times without losing catalyst activity.
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## Abstract An interesting rhodium‐catalyzed asymmetric aqueous Pauson–Khand‐type reaction was developed. A chiral atropisomeric dipyridyldiphosphane ligand was found to be highly effective in this system. This operationally simple protocol allows both catalyst and reactants to be handled under air