Participation of Two Distinct Hydroxylating Intermediates in Iron(III) Porphyrin Complex-Catalyzed Hydroxylation of Alkanes
β Scribed by Nam, Wonwoo; Lim, Mi Hee; Moon, Sun Kyung; Kim, Cheal
- Book ID
- 125521872
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 68 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The catalytic activities of aryl-chlorinated iron tetraarylporphyrins with and without chloro substituents at the I~-pyrrole positions--third and second generation catalysts, respectively--were compared for the hydroxylation of ethylbenzene and cyclohexane by iodosylbenzene. The results reveal that
Three iron(III)-metal-free porphyrin dimers linked covalently with a flexible butoxy chain at the paru position of the two phenyl rings have been prepared and characterized. The hydroxylation of cyclohexane catalyzed by these dimers with molecular oxygen under mild condition has been studied prelimi