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Partially Modified Retro-Inverso Peptides: Development, Synthesis, and Conformational Behavior

✍ Scribed by Fletcher, Matthew David; Campbell, Malcolm M.

Book ID
115504074
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
441 KB
Volume
98
Category
Article
ISSN
0009-2665

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πŸ“œ SIMILAR VOLUMES

Synthesis, Structure and Conformation of
Synthesis, Structure and Conformation of Partially-Modified Retro- and Retro-Inverso ψ[NHCH(CF3)]Gly Peptides
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## Abstract Partially modified retro‐ (PMR) and retro‐inverso (PMRI) ψ[NHCH(CF~3~)]Gly peptides, a conceptually new class of peptidomimetics, have been synthesized in wide structural diversity and variable length by aza‐Michael reaction of enantiomerically pure α‐amino esters and peptides with enan

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The solid-phase synthesis of a novel class of retro and retro-inverso peptides featuring a 2[NHCH(CF 3 )] surrogate of the classical (NHΓ€CO) retro-peptide bond has been accomplished. Wang resin bound a-amino esters 2 were engaged in Michael-type N-additions with 3-(E-enoyl)-1,3-oxazolidin-2one 3, wh