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Partial synthesis of 7-homo-gibberellin A3

✍ Scribed by É. P. Serebryakov; M. Lischewski; G. Adam


Book ID
112440101
Publisher
Springer
Year
1978
Tongue
English
Weight
218 KB
Volume
27
Category
Article
ISSN
1573-9171

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Partial synthesis of tritium-labelled gi
✍ M. Lischewski; G. Adam; H.-W. Liebisch; U. Pleiß 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 French ⚖ 370 KB

The epimeric gibberellin-A 7-aldehydes 1 and 2 were silylated, enolised with KH and 3labelled with -3 H20 to give after desilylation the tritium-labelled epimeric gibberellin-A ?-aldehydes 2 and 2. Subsequent acetylation, oxidation and deacetylation afforded [ 6-3H] gibberellin-A3 (6) and [ 6-3H]6-e

Partial synthesis of [6α-3H]gibberellin-
✍ M. Lischewski; U. Pleiß 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 French ⚖ 108 KB

of Sciences of the GDR, DDR-8051 Dresden, German Democratic Republic s u m y The pbytohomone gibberellin-A was tritium-labell d by a chemical route. The specific aativity o f the [ 6 d -3 H ]gibberellin-,; obtained was 22.5 Ci/nmol.