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Partial Synthesis of 3′-Hydroxy-2′-deoxy-2″,3″,4″,5″-tetrahydroverrucarin A. Verrucarins and roridins, 38th Communication [1]

✍ Scribed by Eric-Andréa Notegen; Motoo Tori; Christoph Tamm

Publisher: John Wiley and Sons
Year: 1981
Tongue: German
Weight: 807 KB
Volume: 64
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19810640132

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✦ Synopsis

Abstract

The macrocyclic trichothecene triester 3′‐hydroxy‐2′‐deoxy‐2",3",4",5"‐tetrahydroverrucarin A (37), has been synthesized starting from the sesquiterpene alcohol verrucarol (3), adipic acid and a derivative of mevalonic acid (14). The latter has been prepared from 4‐(tetrahydro‐2‐pyranyloxy)‐2‐butanone (9).

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