๐”– Bobbio Scriptorium
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Part 1. Efficient Strategies for the Construction of Variably Substituted Bicyclo[5.3.1]undecenones. (AB Taxane Ring Systems).

โœ Scribed by Alain Laurent; Nidia P. Villalva-Servin; Pat Forgione; Peter D. Wilson; David V. Smil; Alex G. Fallis


Publisher
John Wiley and Sons
Year
2004
Weight
116 KB
Volume
35
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Cyclopropylalky
โœ H. LIU; C. A. SHOOK; J. A. JAMISON; M. THIRUVAZHI; T. COHEN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

The Cyclopropylalkylidenecyclopropane Thermal Double Ring Expansion. A Novel Route to the Bicyclo[5.3.1]undecane Skeleton of the AB Ring System of Taxanes. -The mechanism of the reaction is explained by the initial formation of a diradical followed by opening to a homoallylic biradical which closes