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ChemInform Abstract: The Cyclopropylalkylidenecyclopropane Thermal Double Ring Expansion. A Novel Route to the Bicyclo[5.3.1]undecane Skeleton of the AB Ring System of Taxanes.

✍ Scribed by H. LIU; C. A. SHOOK; J. A. JAMISON; M. THIRUVAZHI; T. COHEN

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Cyclopropylalkylidenecyclopropane Thermal Double Ring Expansion. A Novel Route to the Bicyclo[5.3.1]undecane Skeleton of the AB Ring System of Taxanes.

-The mechanism of the reaction is explained by the initial formation of a diradical followed by opening to a homoallylic biradical which closes to the six-membered ring.

-(LIU, H.;

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