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Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (±)-Epibatidine and Analogues

✍ Scribed by Palmgren, Andreas; Larsson, Anna L. E.; Bäckvall, Jan-E.; Helquist, Paul


Book ID
126305795
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
166 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Palladium(II)-Catal
✍ Andreas Palmgren; Anna L. E. Larsson; Jan-E. Baeckvall; Paul Helquist 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (±)-Epibatidine and Analogues. -1,4-Chloroacetoxylation of arenes (I) in the presence of palladium(II) catalyst gives cis-cyclohexenes (III) with high regio-and stereoselectivity. These products are