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ChemInform Abstract: Application of O2-DMSO as Reoxidant in the Pd(II)-Catalyzed 1,4- Oxidation of 5-Substituted 1,3-Cyclohexadienes.

โœ Scribed by M. ROENN; P. G. ANDERSSON; J.-E. BAECKVALL

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium(II)-Catal
ChemInform Abstract: Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (.+-.)-Epibatidine and Analogues.
โœ Andreas Palmgren; Anna L. E. Larsson; Jan-E. Baeckvall; Paul Helquist ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 37 KB ๐Ÿ‘ 1 views

Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (ยฑ)-Epibatidine and Analogues. -1,4-Chloroacetoxylation of arenes (I) in the presence of palladium(II) catalyst gives cis-cyclohexenes (III) with high regio-and stereoselectivity. These products are