𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Palladium(II) assisted alkylation of olefins with stabilized carbanions

✍ Scribed by Hayashi, Tamio; Hegedus, Louis S.


Book ID
126870587
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
249 KB
Volume
99
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Asymmetric palladium-assisted alkylation
✍ A. SolladiΓ©-Cavallo; J.L. Haesslein; Jan-E. BΓ€ckvall πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 207 KB

Palladrum-promoted alkylatron of some alkenes using choral sulfoxidecontalnmg carbanlon as nucleophlles or using optrcally active N,N-dlmethyl-u--phenylethylamlne as ligand together with a non-choral stabilized carbanlon as nucleophlle results in an asymmetric Induction of 10-40X. Palladlunrasslsted

Regioselective alkylation and olefinatio
✍ Bum Sung Lee; Jun Mo Gil; Dong Young Oh πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 56 KB

Treatment of allylphosphonate with LiHMDS, followed by successive addition of chlorotrimethylsilane and carbonyl reagent, afforded dienylsilanes in good yields. 3-Substituted dienylsilanes were obtained by alkylation and olefination of allylic carbanion of 3-trimethylsilylallylphosphonates.