Dipole stabilized α-amino carbanions. II. Alkylation of tetrahydroisoquinolines in the 1-position.
✍ Scribed by A.I. Meyers; Stuart Hellring; Wolter Ten Hoeve
- Book ID
- 104243551
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 169 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
DIPOLE STABILIZED a-AMINO CARBANIONS. II.
📜 SIMILAR VOLUMES
In this study, the overall stability constants of copper(II) complexes with some ␣-amino acids (glycine, DL-alanine, DL-valine, L-leucine, L-asparagine, L-glutamine) were determined by potentiometric titration in water, 25% dioxan-75% water, 35% dioxan-65% water, 50% dioxan-50% water, and 60% dioxan
The formation of the a-substituted radicals 1-9 with the 4pyridyl (?), l-naphthyl(8), and the 2-naphthyl(9) substituent by thermolysis of their dimers 1-3 in solution was investigated. The activation parameters of the homolysis of the central CC bond were obtained from kinetic measurements of the th