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Palladium(II) and platinum(II) complexes containing dimesyloxy-substituted chiral diamines

✍ Scribed by Chin-Chin Lim; K.F. Mok; K.Y. Sim; Pak-Hing Leung

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
365 KB
Volume
8
Category
Article
ISSN
0957-4166

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✦ Synopsis

The physically stable but chemically reactive square-planar complex (+)-[(dichloro){(S,S)-l,4-dimesyloxy-2,3-butanediamine}palladium(II)] and its platinum(lI) analogue have been prepared from the reactions between the dihydrochloride salt of the diamine and K2MCI4 (where M=Pd, Pt) in water. The palladium complex has been analysed by X-ray crystallography. In contrast to their metal complexes, the free diamine ligand and its dihydrochloride salt are unstable and cannot be isolated.

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