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Palladium/Di-1-adamantyl-n-butylphosphine-Catalyzed Reductive Carbonylation of Aryl and Vinyl Halides.

✍ Scribed by Anne Brennfuehrer; Helfried Neumann; Stefan Klaus; Thomas Riermeier; Juan Almena; Matthias Beller

Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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A Straightforward Synthesis of Pyrazolin
A Straightforward Synthesis of Pyrazolines and Pyrazoles: Palladium-Catalyzed Carbonylative Vinylation–Cyclocondensation Reactions of Aryl Halides
✍ Xiao-Feng Wu; Helfried Neumann; Matthias Beller 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB

## Abstract A novel consecutive one‐pot synthesis of pyrazolines and pyrazoles starting from simple aryl halides, styrenes, carbon monoxide, and hydrazines has been established. Palladium‐catalyzed carbonylative vinylation of aryl halides gave the corresponding chalcones, which are trapped in situ