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Palladium(0)-Catalyzed Regioselective Synthesis of α-Dehydro-β-amino Esters from Amines and Allyl Acetates: Synthesis of a α-Dehydro-β-amino Acid Derived Cyclic Peptide as a Constrained β-Turn Mimic

✍ Scribed by Rajesh, S.; Banerji, Biswadip; Iqbal, Javed

Book ID: 127079163
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 153 KB
Volume: 67
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo010981d

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Palladium(0)-Catalyzed Regioselective Sy

Palladium(0)-Catalyzed Regioselective Synthesis of α-Dehydro-β-amino Esters from Amines and Allyl Acetates: Synthesis of a α-Dehydro-β-amino Acid Derived Cyclic Peptide as a Constrained β-Turn Mimic.

✍ S. Rajesh; Biswadip Banerji; Javed Iqbal 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 312 KB 👁 1 views

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An Efficient Synthesis of Achiral and Ch

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## Abstract A very simple and efficient synthesis of 3‐amino‐1,5‐dihydro‐2__H__‐pyrrol‐2‐ones is reported. These cyclic dehydro‐amino acid derivatives with a stereogenic center at the 5‐position were obtained by the addition of two equivalents of amine to β,γ‐unsaturated keto esters. These cyclic e