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An Efficient Synthesis of Achiral and Chiral Cyclic Dehydro-α-Amino Acid Derivatives Through Nucleophilic Addition of Amines to β,γ-Unsaturated α-Keto Esters.

✍ Scribed by Francisco Palacios; Javier Vicario; Domitila Aparicio

Publisher
John Wiley and Sons
Year
2006
Weight
25 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

An Efficient Synthesis of Achiral and Ch
An Efficient Synthesis of Achiral and Chiral Cyclic Dehydro-α-Amino Acid Derivatives Through Nucleophilic Addition of Amines to β,γ-Unsaturatedα-Keto Esters
✍ Francisco Palacios; Javier Vicario; Domitila Aparicio 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB

## Abstract A very simple and efficient synthesis of 3‐amino‐1,5‐dihydro‐2__H__‐pyrrol‐2‐ones is reported. These cyclic dehydro‐amino acid derivatives with a stereogenic center at the 5‐position were obtained by the addition of two equivalents of amine to β,γ‐unsaturated keto esters. These cyclic e