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Palladium η3-allyl complex with sorbic acid: Kinetics and mechanism of protodemetalation in aqueous solutions

✍ Scribed by D. A. Surovtseva; D. A. Orlov; T. A. Morozova; A. V. Krylov; A. P. Belov

Book ID
110170799
Publisher
Springer
Year
2006
Tongue
English
Weight
190 KB
Volume
47
Category
Article
ISSN
0023-1584

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✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h