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Palladium Pincer Complexes with Reduced Bond Angle Strain: Efficient Catalysts for the Heck Reaction

✍ Scribed by Yoon, Myeong Sik; Ryu, Dowook; Kim, Jeongryul; Ahn, Kyo Han

Book ID
125522918
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
101 KB
Volume
25
Category
Article
ISSN
0276-7333

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✍ Kazuhiro Takenaka; Yasuhiro Uozumi 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB 👁 2 views

## Abstract The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140 °C in the presence of 1 mol ppb of the pincer palladium complex [4‐__tert__‐butyl‐2,6‐bis{(3__R__,7a__S__)‐2‐phenylhexahydro‐1__H__‐pyrrolo[1,2‐__c__]imidazole‐1‐on‐3‐yl}phenyl]chloropalladium to give