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Palladium mediated allylic mitsunobu displacement: stereocontrolled synthesis of hepoxilin A3 and trioxilin A3 methyl esters

โœ Scribed by Sun Lumin; J.R. Falck; Jorge Capdevila; Armando Karara


Book ID
103405050
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
249 KB
Volume
33
Category
Article
ISSN
0040-4039

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A Pd-catalyzed allylation of 3-substituted 1-cyclopentenolates with readily obtainable and storable v-monosubstituted (Z)-allylic acetates in a 1:l ratio in the presence of 2 mol % of Pd(PPh3)4 featuring high yields and high stereo-and regioselectivities has been developed and applied to the synthes