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Palladium-Indium-Indium(III) Chloride-Mediated Allyl Cross-Coupling Reactions Using Allyl Acetates

✍ Scribed by Phil Ho Lee; Dong Seomoon; Kooyeon Lee; Sundae Kim; Hyunseok Kim; Hyun Kim; Eunkyong Shim; Miae Lee; Seokju Lee; Misook Kim; Madabhushi Sridhar

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
163 KB
Volume
346
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

Allylindiums in situ generated by reductive transmetalation of π‐allylpalladium(II) complexes, obtained from allyl acetates and palladium(0) catalyst, with indium and indium(III) chloride are effective nucleophilic cross‐coupling partners in Pd‐catalyzed allyl cross‐coupling reactions with a variety of electrophilic cross‐coupling partners.

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