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Inter- and Intramolecular Palladium-Catalyzed Allyl Cross-Coupling Reactions Using Allylindium Generated in situ from Allyl Acetates, Indium, and Indium Trichloride.

✍ Scribed by Dong Seomoon; Kooyeon Lee; Hyunseok Kim; Phil Ho Lee

Publisher
John Wiley and Sons
Year
2007
Weight
42 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Inter‐ and intramolecular palladium‐catalyzed allyl cross‐coupling reactions using allylindium generated in situ by treatment of allyl acetates with indium and indium trichloride in the presence of Pd^0^ catalyst and __n__BuNMe~2~ in DMF were successfully demonstrated. Allylindium speci

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## Abstract Allylindiums __in situ__ generated by reductive transmetalation of π‐allylpalladium(II) complexes, obtained from allyl acetates and palladium(0) catalyst, with indium and indium(III) chloride are effective nucleophilic cross‐coupling partners in Pd‐catalyzed allyl cross‐coupling reactio