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Palladium-catalyzed synthesis of 1,2-dihydro-4(3H)-carbazolones. Formal total synthesis of murrayaquinone A

✍ Scribed by Tricia L Scott; Björn C.G Söderberg

Book ID
104205575
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
287 KB
Volume
59
Category
Article
ISSN
0040-4020

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✦ Synopsis

Two sequential palladium-catalyzed reactions are the key steps in a novel synthetic route to 1,2-dihydro-4(3H)-carbazolones. The steps are an intermolecular Stille cross-coupling followed by a reductive N-heteroannulation. A formal total synthesis of murrayaquinone A, employing this sequence, is reported.

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Novel palladium-catalyzed synthesis of 1,2-dihydro-4(3H)-carbazolones
✍ Tricia L. Scott; Björn C.G. Söderberg 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 122 KB

Two sequential palladium-catalyzed reactions are the key steps in a novel synthetic route to carbazolones, an intermolecular Stille coupling followed by a recently developed palladium-catalyzed reductive N-heteroannulation. A number of functionalized 1,2-dihydro-4(3H)-carbazolones were prepared usin