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Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

✍ Scribed by Oshima, Kazuyuki; Ohmura, Toshimichi; Suginome, Michinori

Book ID
121453886
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
851 KB
Volume
133
Category
Article
ISSN
0002-7863

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Palladium-catalyzed intramolecular cyano
Palladium-catalyzed intramolecular cyanoboration of allenes leading to the regioselective synthesis of Ξ²-cyanoallylboranes
✍ Akihiko Yamamoto; Yuto Ikeda; Michinori Suginome πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 381 KB

Inter-and intramolecular addition of the boron-cyanide bond of cyanoboranes across a carbon-carbon double bond of allenes proceeded in the presence of palladium catalysts, affording allylboranes that bear a cyano group at the b-position regioselectively.