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A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study

✍ Scribed by Abe, Yoko; Kuramoto, Kei; Ehara, Masahiro; Nakatsuji, Hiroshi; Suginome, Michinori; Murakami, Masahiro; Ito, Yoshihiko

Book ID: 125484825
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 857 KB
Volume: 27
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om070110f

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## Abstract Methyl 1‐methylprop‐2‐ynyl carbonate reacts with 3‐ and 4‐substituted benzene‐1,2‐diols to give 2,3‐dihydro‐3‐methyl‐2‐methylidene‐1,4‐benzodioxines, as a mixture of regioisomers in the case of methoxy‐substituted diphenol, and a single regioisomer for the nitro‐ and the formyl‐substitu