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Palladium-Catalyzed Regio- and Diastereoselective Allylic Alkylation with Azlactones Using Triphenylarsine.

✍ Scribed by Motoi Kawatsura; Daiji Ikeda; Tamiko Ishii; Yuji Komatsu; Junichi Uenishi

Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Diastereoselective a
Palladium-Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates
✍ Manfred Braun; Thorsten Meier; Frank Laicher; Panos Meletis; Mesut Fidan πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 297 KB πŸ‘ 2 views

## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladium‐catalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenyl‐ and dimethyl‐substituted allylic substrates **1a** and **1b** are reacted with cyclohexanone