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ChemInform Abstract: Palladium-Catalyzed Regio- and Diastereoselective Allylic Alkylation in Ionic Liquids.

✍ Scribed by Motoi Kawatsura; Hideyuki Nobuto; Shunsuke Hayashi; Takuya Hirakawa; Daiji Ikeda; Toshiyuki Itoh

Publisher: John Wiley and Sons
Year: 2012
Weight: 34 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201205027

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The room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate is used as a recyclable alternative to dipolar aprotic solvents for the regioselective alkylation at the heteroatom of indole (I) and 2-naphthol (V) using alkyl halides (II). The related ionic liquid 1-butyl-3-methylim