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Palladium-catalyzed phenylation of allylic 1-perfluoroalkyl alcohols

✍ Scribed by Konrad Von Werner

Book ID
108354342
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
197 KB
Volume
136
Category
Article
ISSN
0022-328X

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## Abstract Treatment of allylic alcohols containing a 1,1‐disubstituted alkene with a palladium catalyst and hydrogen gas (1β€…bar) results in facile isomerization to their corresponding trisubstituted (__E__)‐allylic alcohols, along with small amounts of the corresponding hydrogenated products.