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Palladium-catalyzed N,N′-diphenylurea synthesis from nitrobenzene, aniline, and carbon monoxide. Part 3. Evidence of carbamoyl intermediate

✍ Scribed by Kye Duck Kim; Sang Moo Lee; Nag Sug Cho; Jae Seung Oh; Chul Woo Lee; Jae Sung Lee

Publisher
Elsevier Science
Year
1992
Weight
379 KB
Volume
75
Category
Article
ISSN
0304-5102

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The influence of aniline (PhNH,) on the reductive carbonylation of nitrobenzene (PhNO,) by carbon monoxide and an excess of methanol, catalyzed by (w/w % with respect to PhNO,): sulfur (IO>, sodium methoxide (2). ammonium metavanadate (0. I), at 423 + 2 K and starting pressure of CO 13 MPa (298 K) w