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A highly selective palladium-catalyzed synthesis of N,N'-diphenylurea from nitrobenzene, aniline and carbon monoxide

✍ Scribed by Jae S. Lee; Chul W. Lee; Sang M. Lee; Kwang H. Park

Publisher
Elsevier Science
Year
1990
Weight
336 KB
Volume
61
Category
Article
ISSN
0304-5102

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The influence of aniline (PhNH,) on the reductive carbonylation of nitrobenzene (PhNO,) by carbon monoxide and an excess of methanol, catalyzed by (w/w % with respect to PhNO,): sulfur (IO>, sodium methoxide (2). ammonium metavanadate (0. I), at 423 + 2 K and starting pressure of CO 13 MPa (298 K) w