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Palladium-catalyzed Inter- and Intramolecular Hydroamination of Methylenecyclopropanes with Amines

✍ Scribed by I. Nakamura; H. Itagaki; Y. Yamamoto


Book ID
110329626
Publisher
Springer US
Year
2001
Tongue
English
Weight
142 KB
Volume
37
Category
Article
ISSN
0009-3122

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Inter- and intramolecular palladium-cata
✍ Naofumi Tsukada; Akinori Shibuya; Itaru Nakamura; Haruo Kitahara; Yoshinori Yama πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 553 KB

The inter-and intrarnolecular additions of pronucleophiles to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh3) 4, affording hydrocarbonation products in good to high yields. The ring opening of methylenecyclopropanes mainly occurred at the distal position to