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Palladium-Catalyzed Insertion of CO2 into Vinylaziridines: New Route to 5-Vinyloxazolidinones

✍ Scribed by Fontana, Francesco; Chen, C. Chun; Aggarwal, Varinder K.


Book ID
115447682
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
1006 KB
Volume
13
Category
Article
ISSN
1523-7060

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## Abstract Pd‐Catalyzed amination of 3,5‐dibromo‐ and 3,5‐dichloropyridine (**1a** and **1b**, resp.) with linear polyamines **2** leads to the formation of a new family of pyridine‐containing macrocycles **3** with an ‘__exo__’‐oriented pyridine N‐atom (__Schemes 1__ and __2__). The dependence of