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Palladium catalyzed hydrosulfination of allenes with tosylhydrazine leading to allylsulfones

โœ Scribed by Shin Kamijo; Mohammad Al-Masum; Yoshinori Yamamoto


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
207 KB
Volume
39
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The palladium catalyzed reaction ofallenes 1 with tosylhydrazinein the presenceof 1 equiv AcOH and 10 mol% dppf gave the corresoondin~ allylsufones 2 in moderate to good yields.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Palladium-Catalyzed
โœ S. KAMIJO; M. AL-MASUM; Y. YAMAMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

## 1998 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600 ## 18 -110 Palladium-Catalyzed Hydrosulfination of Allenes with Tosylhydrazine Leading to Allylsulfones. -The Pd-catalyzed reaction of the monosubstituted allenes (I)

Palladium-catalyzed intramolecular cyano
โœ Akihiko Yamamoto; Yuto Ikeda; Michinori Suginome ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 381 KB

Inter-and intramolecular addition of the boron-cyanide bond of cyanoboranes across a carbon-carbon double bond of allenes proceeded in the presence of palladium catalysts, affording allylboranes that bear a cyano group at the b-position regioselectively.