Palladium-Catalyzed Heck Reaction on 1-Alkoxy-1,3-dienes: A Regioselective γ-Arylation of α,β-Unsaturated Carbonyl Compounds
✍ Scribed by Deagostino, Annamaria; Prandi, Cristina; Venturello, Paolo
- Book ID
- 127300265
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 62 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1523-7060
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Arylation of 2-substituted 2-alkenals and 3-substituted 2-cyclohexen-and 2-cyclopenten-l-ones can effectively and regioselectively proceed at their y-position by treatment with aryl bromides in the presence of a palladium catalyst and a base.