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Palladium-Catalyzed Heck Arylations of Allyl Alcohols in Ionic Liquids: Remarkable Base Effect on the Selectivity.

โœ Scribed by Vincenzo Calo; Angelo Nacci; Antonio Monopoli; Valentina Ferola


Publisher
John Wiley and Sons
Year
2007
Weight
53 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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The effect of the natural bite angle (ฮฒ n ) of diphosphane li-angle of the ligand becomes larger. This results in an increasing selectivity at larger bite angles, but at very large gands on catalyst selectivity and activity in the palladiumcatalyzed allylic alkylation was investigated. The selectivi