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Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides

✍ Scribed by Paul, Frederic; Patt, Joe; Hartwig, John F.


Book ID
119948646
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
262 KB
Volume
116
Category
Article
ISSN
0002-7863

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Palladium-catalyzed cross-coupling react
✍ Kohei Tamao; Kenji Kobayashi; Yoshihiko Ito 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 254 KB

Alkenyl-monoalkoxydimethylsilanes, dialkoxymethylsilanes, and trialkoxysilanes undergo palladium-catalyzed cross-coupling reaction with alkenyl and aryl halides in the presence of tetra-n-butylammonium fluoride. A one-pot transformation of a homopropargyl alcohol to regio-and stereo-defined trisubs