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Palladium-Catalyzed Formal [4 + 2] Cycloaddition of o-Xylylenes with Olefins.

✍ Scribed by Ryoichi Kuwano; Takenori Shige


Publisher
John Wiley and Sons
Year
2007
Weight
34 KB
Volume
38
Category
Article
ISSN
0931-7597

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Novel Palladium-Catalyzed Formal [3 + 2] Cycloaddition via Hydrocarbonation Reactions of Allenes. -The palladium-catalyzed reaction of activated olefins (I), (IV), (VI), and (VIII) with allenes (II) and (Xa), bearing an activated methine at the carbon chain terminus, gives cyclopentanes with good t