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Palladium-Catalyzed Cyclocarbonylation of Terminal and Internal Alkynols to 2(5 H )-Furanones

โœ Scribed by Yu, Wing-Yiu; Alper, Howard


Book ID
126307116
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
203 KB
Volume
62
Category
Article
ISSN
0022-3263

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Synthesis of 3-silyl-2(5H)-furanone by r
โœ Yukimasa Fukuta; Isamu Matsuda; Kenji Itoh ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 87 KB

3-Silyl-2(5H)-furanones are readily formed by the rhodium-catalyzed cyclocarbonylation of propargyl alcohol derivatives bearing a trialkylsilyl group on the terminal sp-carbon under hydroformylation conditions. The following two requirements must be satisfied for the success of this protocol; (i) th