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Palladium-Catalyzed Cycloalkylations of 2-Bromo-1, n -dienes with Organoboronic Acids

✍ Scribed by Oh, Chang Ho; Sung, Hye Rhyan; Park, Su Jin; Ahn, Kyo Han

Book ID
127373948
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
98 KB
Volume
67
Category
Article
ISSN
0022-3263

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Palladium-catalyzed cascade cyclization-
Palladium-catalyzed cascade cyclization-coupling reactions of 2-bromo-1,6-enynes with organoboronic acids
✍ Chang Ho Oh; Young Mook Lim πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 257 KB

2-Bromo-1,6-enynes 5 with a palladium catalyst would form the alkenylpalladium intermediates via an intramolecular Heck reaction, which were cross-coupled with various organoboronic acids 8 to give the cyclization-coupling products 6 in synthetically valuable yields.