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Palladium-catalyzed cross-coupling reaction of bis(ferrocenyl)mercury with aryl iodides

✍ Scribed by Alexey V Tsvetkov; Gennadij V Latyshev; Nikolai V Lukashev; Irina P Beletskaya

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
217 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cross-coupling reactions of bis(ferrocenyl)mercury with aryl-and heteroaryl iodides were shown to be easy and convenient for the synthesis of monoarylsubstituted ferrocenes in high yields. The highly selective substitution of iodine atom in iodobromoarenes by the ferrocenyl unit was demonstrated.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Palladium-Catalyzed
ChemInform Abstract: Palladium-Catalyzed Cross-Coupling Reaction of Bis(ferrocenyl)mercury with Aryl Iodides.
✍ Alexey V. Tsvetkov; Gennadij V. Latyshev; Nikolai V. Lukashev; Irina P. Beletska πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Efficient Copper-Catalyzed Cross-Couplin
Efficient Copper-Catalyzed Cross-Coupling Reaction of Alkynes with Aryl Iodides
✍ Che-Hung Lin; Yu-Jen Wang; Chin-Fa Lee πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 110 KB πŸ‘ 1 views

## Abstract A copper‐catalyzed cross‐coupling reaction of alkynes with aryl iodides is described. The system tolerates a broad range of functional groups and enables the use of sterically demanding substrates with only 1.0–2.5 mol‐% of Cu~2~O and 1.0–2.5 mol‐% of xantphos as the catalyst.