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Palladium-catalyzed cross-coupling of allylic carbonates with alkenylfluorosilanes in the absence of fluoride ion

✍ Scribed by Hayao Matsuhashi; Yasuo Hatanaka; Manabu Kuroboshi; Tamejiro Hiyama


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
112 KB
Volume
36
Category
Article
ISSN
0040-4039

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Palladium-catalyzed cross-coupling react
✍ Kohei Tamao; Kenji Kobayashi; Yoshihiko Ito πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 254 KB

Alkenyl-monoalkoxydimethylsilanes, dialkoxymethylsilanes, and trialkoxysilanes undergo palladium-catalyzed cross-coupling reaction with alkenyl and aryl halides in the presence of tetra-n-butylammonium fluoride. A one-pot transformation of a homopropargyl alcohol to regio-and stereo-defined trisubs