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Palladium-Catalyzed Coupling/Cyclization Reactions of Allene-Substituted Lactams

✍ Scribed by Willem F.J. Karstens; Floris P.J.T. Rutjes; Henk Hiemstra

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
573 KB
Volume
38
Category
Article
ISSN
0040-4039

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Palladium(0)-Catalyzed Coupling Cyclization of Functionalized Allenes with Hypervalent Iodonium Salts. -The title reaction of allenic alcohols and amines provides the corresponding heterocyclic compounds in good yields. Cyclization of allenic acids (IV) leads to formation of lactones (V), which are