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Palladium-Catalyzed Coupling Reactions of Thioimidate N-Oxides: Access to α-Alkenyl- and α-Aryl-Functionalized Cyclic Nitrones

✍ Scribed by Julie Schleiss; Patrick Rollin; Arnaud Tatibouët


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
318 KB
Volume
49
Category
Article
ISSN
0044-8249

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Palladium-Catalyzed Decarboxylative sp-s
✍ Hyunseok Kim; Phil Ho Lee 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 2 views

## Abstract Palladium‐catalyzed decarboxylative __sp‐sp__^2^ cross‐coupling reactions of aryl and vinyl halides and triflates with α,β‐ynoic acids using silver oxide have been developed. A variety of α,β‐ynoic acids were readily decarboxylated in the presence of silver oxide and then, generated __i