Palladium-Catalyzed Carbonylative Dimerization of Styrenes to 1,5-Diarylpent-1-en-3-ones
✍ Scribed by Dr. Xiao-Feng Wu; Dr. Helfried Neumann; Prof. Dr. Matthias Beller
- Book ID
- 112006499
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 334 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1861-4728
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📜 SIMILAR VOLUMES
Dimerization of styrene was investigated in ionic liquids and organic solvents with the catalysis of several palladium-Lewis acids catalyst systems. Pd(OAc) 2 /Cu(OTf) 2 and Pd(OAc) 2 /In(OTf) 3 in 1-butyl-3-methylimidazolium hexafluorophosphate were found to be effective catalyst systems towards th
a b s t r a c t 2-Bromobenzaldehyde is carbonylatively cyclized with primary amines under carbon monoxide pressure in DMF at 100 °C in the presence of a catalytic amount of a palladium catalyst to give the corresponding isoindolin-1-ones in moderate to high yields.
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