𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Palladium-catalyzed carbonylative coupling of benzyl chlorides with aryl boronic acids in aqueous media

✍ Scribed by Xiao-Feng Wu; Helfried Neumann; Matthias Beller

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
885 KB
Volume
51
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Palladium–imidazolium-catalyzed carbonyl
Palladium–imidazolium-catalyzed carbonylative coupling of aryl diazonium ions and aryl boronic acids
✍ Merritt B. Andrus; Yudao Ma; Yunfu Zang; Chun Song 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 209 KB

Palladium(II) acetate and N, N-bis-(2,6-diisopropylphenyl)dihydroimidazolium chloride (2 mol%) were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones. Optimal conditions include carbon monoxide (1 atm) in 1,4-dioxane at

Palladium-Catalyzed Carbonylative Suzuki
Palladium-Catalyzed Carbonylative Suzuki Coupling of Benzyl Halides with Potassium Aryltrifluoroborates in Aqueous Media
✍ Xiao-Feng Wu; Helfried Neumann; Matthias Beller 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 1 views

## Abstract A general palladium‐catalyzed carbonylative cross‐coupling reaction of benzyl chlorides with potassium aryltrifluoroborates in water has been developed. Applying this improved methodology 16 different 1,2‐diarylethanones have been synthesized in 40–89% yield.