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Palladium-Catalyzed Carbonylative Annulation Reaction of 2-(1-Alkynyl)benzenamines: Selective Synthesis of 3-(Halomethylene)indolin-2-ones

✍ Scribed by Tang, Shi; Yu, Quan-Fu; Peng, ; Li, Jin-Heng; Zhong, Ping; Tang, Ri-Yuan

Book ID: 127211466
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 77 KB
Volume: 9
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol701450n

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## Abstract 3‐Sulfenylindoles can be efficiently prepared in moderate to good yields from 2‐(1‐alkynyl)benzenamines and disulfides using the palladium/air catalytic systems. The study also provides a useful route to the synthesis of fipronil analogues.

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