𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Palladium-Catalyzed Annulation of 2-(1-Alkynyl)benzenamines with Disulfides: Synthesis of 3-Sulfenylindoles

✍ Scribed by Yan-Jin Guo; Ri-Yuan Tang; Jin-Heng Li; Ping Zhong; Xing-Guo Zhang


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
167 KB
Volume
351
Category
Article
ISSN
1615-4150

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

3‐Sulfenylindoles can be efficiently prepared in moderate to good yields from 2‐(1‐alkynyl)benzenamines and disulfides using the palladium/air catalytic systems. The study also provides a useful route to the synthesis of fipronil analogues.


📜 SIMILAR VOLUMES


Palladium(0)-Catalyzed Asymmetric Synthe
✍ Magali Massacret; Paul Lhoste; Denis Sinou 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 149 KB 👁 1 views

Reaction of (Z)-1,2-bis(methoxycarbonyloxy)but-2-ene ( 2) of (S)-MeOBIPHEP as the chiral ligand and N,N-bis(ptolylsulfonyl)-o-phenylenediamine (1i) as the nucleophile led with various N,N-bis(arylsulfonyl)-o-phenylenediamines 1 was catalyzed by a palladium complex associated with chiral to the highe

Palladium-Catalyzed Trimerizations of Te
✍ Yao-Ting Wu; Wei-Chih Lin; Chia-Ju Liu; Chuan-Yi Wu 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB 👁 2 views

## Abstract Various 1,3‐diaryl‐2‐arylethynyl‐1,3‐butadienes **7** have been prepared by the Pd‐catalyzed trimerization of arylalkynes **4**. Their structures and stereochemistry have been confirmed by X‐ray crystal analyses. This procedure provides high regioselectivity to generate adducts __Z__‐**

Lewis Acid-Catalyzed [3+4] Annulation of
✍ Olga A. Ivanova; Ekaterina M. Budynina; Alexey O. Chagarovskiy; Alexey E. Kaplun 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 348 KB 👁 1 views

## Abstract A novel Lewis acid‐catalyzed [3+4] annulation of 2‐(heteroaryl)cyclopropane‐1,1‐dicarboxylates with cyclopentadiene is reported. This reaction proceeds __via__ an electrophilic attack of the Lewis acid‐activated donor‐acceptor cyclopropane onto cyclopentadiene followed by Friedel–Crafts